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Diethyl chlorophosphate

CAS#[814-49-3]
G-codeGEO-02876
EC number212-396-4
Molecular formulaC4H10ClO3P
Molecular weight172.55
Synonyms Diethylphosphoryl chloride ; Diethyl chlorophosphonate ; O,O-Diethyl phosphorochloridate ; Phosphoric acid diethyl ester chloride ; Phosphorochloridic acid O,O-diethyl ester ; Diethyl phosphorochloridate
Structure of Diethyl chlorophosphate
General description

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Specification

AppearanceClear colourless to light brown liquid
Puritymin. 98,0%
Storage conditionsTightly closed container store at 4°C (long-term storage)

Structural identification

CAS#[814-49-3]
G-codeGEO-02876
EC number212-396-4
SMILESO=P(OCC)(Cl)OCC
InChIInChI=1S/C4H10ClO3P/c1-3-7-9(5,6)8-4-2/h3-4H2,1-2H3
InChI KeyInChIKey=LGTLXDJOAJDFLR-UHFFFAOYSA-N
Download structure as .mol

Regulatory Information

Transport InformationORGANOPHOSPHORUS COMPOUND, LIQUID, TOXIC, N.O.S. UN3278 6.1/PG I
GHS pictogram
GHS06_toxic
Signal WordDanger
Hazard Statements
H300 - H310 - H331

H300 – Fatal if swallowed.
H310 – Fatal in contact with skin.
H331 – Toxic if inhaled.

Precautionary Statements
P262 - P264 - P280 - P301+P310 - P302+P352+P310 - P304+P340 - P311

P262 – Do not get in eyes, on skin, or on clothing.
P264 – Wash … thoroughly after handling.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 – IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352+P310 – IF ON SKIN: Wash with plenty of water. Immediately call a POISON CENTER/ doctor.
P304+P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P311 – Call a POISON CENTER or doctor/physician.

Product categorization

Main category

Description

By using Diethyl chlorophosphate, some ketones can be converted to enol phosphates which can be reduced to alkenes/alkanes or coupled with…

Original article: Diethyl chlorophosphate – general description and application

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