N-Methyl-tert-butylamine
N-tert-Butylmethylamine
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Regulatory Information
H225 – Highly flammable liquid and vapour.
H302+H312+H332 – Harmful if swallowed, in contact with skin or if inhaled.
H314 – Causes severe skin burns and eye damage.
P210 – Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 – Keep container tightly closed.
P240 – Ground/bond container and receiving equipment.
P241 – Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash … thoroughly after handling.
P270 – Do no eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312+P330 – IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340+P310 – IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 – Take off contaminated clothing and wash before reuse.
P370+P378 – In case of fire: Use … for extinction.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to …
Product categorization
Description
N-Methyl-tert-butylamine is a useful chemical compound with a variety of research applications. We are pleased to offer high quality N-Methyl-tert-butylamine in various sizes (for research, pilot-scale, or production applications) from milligrams to multi-kilogram batches, making it easy for you to choose the right amount to suit your needs.
N-Methyl-tert-butylamine as a secondary amine can undergo chemical reactions to form desired amines and amides. It was used in a SAR study related to N,N-disubstitutions of the terminal…
Show full descriptionGeneral description and preparation:
N-Methyl-tert-butylamine [14610-37-8] (N-tert-Butylmethylamine or N-Methyl-2-methyl-2-propanamine) is a secondary amine and it is a colorless to pale yellow with the boiling point of 69 °C.[1] It is a highly flammable liquid and vapor. It is corrosive irritant that is harmful if inhaled, swallowed or in contact with skin. N-Methyl-tert-butylamine can be prepared by reductive N-methylation of tert-butylamine with carbon dioxide and diphenylsilane catalysed with caesium carbonate via initially formed t-butylformamide.[2] It can be also obtained from t-butylformamide by reduction with lithium aluminium tetrahydride or catalytic hydrogenation.[3]Application of N-Methyl-tert-butylamine:
N-Methyl-tert-butylamine as a secondary amine can undergo chemical reactions to form desired amines[4] and amides[5]. It was used in a SAR study related to N,N-disubstitutions of the terminal acetamide on pyrazolopyrimidines.[6] It was used in a new approach to pyrrolo[3,4-b]indole ring system via tri-n-butyltin hydride induced 1,5-radical translocation and 5-endo-trig cyclization of carboxamide formed from 3-trifluoroacetylindole and N-methyl-tert-butylamine.[7]Product categorization (Chemical groups):
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