Palladium in both oxidation states (0, +2) is widely utilized as a catalyst in various synthetic methods and is also used in the preparation of many organic compounds. In particular, palladium on carbon is a versatile catalyst that speeds up heterogeneous catalytic processes like hydrogenation, dehydrogenation, and petroleum cracking. A large number of carbon–carbon bond-forming reactions in organic chemistry are facilitated by palladium metal catalysts.

Palladium Catalysts – structures

Tetrakis(triphenylphosphine)palladium(0) Bis(benzonitrile)palladium(II)chloride Dichlorobis(triphenylphosphine)palladium(II) Bis(acetonitrile)palladium(II) chloride

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Product name CAS# Appearance MF MW(g/mol)
1,1′-Bis(diphenylphosphino)ferrocene palladium(II)dichloride 72287-26-4 Brown red powder (C17H14P)2Fe · PdCl2 731,7
1,1′-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex 95464-05-4 Brown red powder C35H30Cl4FeP2Pd 816,65
Dichlorobis(triphenylphosphine)palladium(II) 13965-03-2 Yellow powder C36H30Cl2P2Pd 701,89
Tetrakis(triphenylphosphine)palladium(0) 14221-01-3 Yellow powder C72H60P4Pd 1155,57
Bis(dibenzylideneacetone)palladium 32005-36-0 Purple powder C34H28O2Pd 575
Tris(dibenzylideneacetone)dipalladium-chloroform adduct 52522-40-4 Black purple powder C52H43Cl3O3Pd2 1035,08
Tris(dibenzylideneacetone)dipalladium 51364-51-3 Black purple powder C51H42O3Pd2 915,7
Bis(acetonitrile)palladium(II) chloride 14592-56-4 Golden yellow powder C4H6Cl2N2Pd 259,41
Dichloro[1,1′-bis(di-t-butylphosphino)ferrocene]palladium(II),98% 95408-45-0 Yellow to red powder C26H44Cl2FeP2Pd 651,75
Bis(benzonitrile)palladium(II)chloride 14220-64-5 Yellow powder C14H10Cl2N2Pd 383,55
Bis(tricyclohexylphosphine)palladium(II) Dichloride 29934-17-6 Light yellow powder C36H66Cl2P2Pd 738,19
Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II) 19978-61-1 White powder C26H24Cl2P2Pd 575,74
Dichloro(1,3-bis(diphenylphosphino)propane)palladium(II) 59831-02-6 Light yellow powder C27H26Cl2P2Pd 589,77
Dichloro[1,4-bis(diphenylphosphino)butane]palladium(II) 29964-62-3 Light yellow to pale yellow green powder C28H28Cl2P2Pd 603,8
Dichloro-[1,3-bis(diisopropylphenyl)-2-imidazolidinylidene]-(3-chloropyridyl)palladium(II) 927706-57-8 Beige powder C32H42Cl3N3Pd 681,47
XPhos Pd G1 / Chloro(2-dicyclohexylphosphino-2′,4′,6′-tri-i-propyl-1,1′-biphenyl)[2-(2-aminoethyl)phenyl] palladium(II) methyl-t-butylether adduct 1028206-56-5 White powder C41H59ClNPPd 738,76
XPhos Pd G2 / Chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)(2′-amino-1,1′-biphenyl-2-yl)palladium(II) 1310584-14-5 White powder C45H59ClNPPd 786,8
XPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-2′,4′,6′-tri-i-propyl-1,1′-biphenyl)(2′-amino-1,1′-biphenyl-2-yl)palladium(II) 1445085-55-1 White powder C46H62NO3PPdS 846,45
XPhos Pd G4 / Methanesulfonato(2-dicyclohexylphosphino-2′,4′,6′-tri-i-propyl-1,1′-biphenyl)(2′-methylamino-1,1′-biphenyl-2-yl)palladium(II) 1599466-81-5 cream color powder C47H64NO3PPdS 860,48
Chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)(2′-amino-1,1′-biphenyl-2-yl)palladium(II) 1375325-68-0 Black gray powder C42H53ClNO2PPd 776,72
RuPhos Pd G1 / Chloro(2-dicyclohexylphosphino-2′,6′-di-i-propoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl] palladium(II),methyl-t-butylether adduct 1028206-60-1 White powder C38H53ClNO2PPd 728,68
RuPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-2′,6′-di-i-propoxy-1,1′-biphenyl)(2′-amino-1,1′-biphenyl-2-yl)palladium(II) 1445085-77-7 White to light yellow powder C43H56NO5PPdS 836,37
RuPhos Pd G4 / Methanesulfonato(2-dicyclohexylphosphino-2′,6′-di-i-propoxy-1,1′-biphenyl)(2′-methylamino-1,1′-biphenyl-2-yl)palladium(II) 1599466-85-9 White powder C44H58NO5PPdS 850,4
BrettPhos Pd G1 / Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2′,4′,6′-tri-i-propyl-1,1′-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) 1148148-01-9 White powder C43H63ClNO2PPd 798,81
BrettPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-tri-i-propyl-1,1′-biphenyl)(2′-amino-1,1′-biphenyl-2-yl)palladium(II) 1470372-59-8 cream color powder C48H66NO5PPdS 906,5
BrettPhos Pd G4 / Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-tri-i-propyl-1,1′-biphenyl)(2′-methylamino-1,1′-biphenyl-2-yl)palladium(II) 1599466-83-7 Rice white powder C49H68NO5PPdS 920,53
P(tBu)3 Pd G2 / Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II) 1375325-71-5 Yellow powder C24H37ClNPPd 512,4
P(t-Bu)3 Pd G3 1445086-17-8 cream color powder C25H40NO3PPdS 572,05
P(t-Bu)3 Pd G4 / Methanesulfonato(tri-t-butylphosphino)(2′-methylamino-1,1′-biphenyl-2-yl)palladium(II) 1621274-11-0 White powder C26H42NO3PPdS 586,08
PCy3 Pd G2 / Chloro[(tricyclohexylphosphine)(2′-aminobiphenyl-2-yl)palladium(II) 1353658-81-7 Light pink powder C30H43ClNPPd 590,52
PCy3 Pd G3 / Methanesulfonato(tricyclohexylphosphine)(2′-amino-1,1′-biphenyl-2-yl)palladium(II) 1445086-12-3 creamy-white powder C31H46NO3PPdS 650,16
XantPhos Pd G2 / Chloro[(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)(2-amino-1,1-biphenyl-2-yl)palladium(II) 1375325-77-1 Light yellow powder C51H42ClNOP2Pd 888,71
Xantphos Pd G3 1445085-97-1 light yellow C52H45NO4P2PdS 948,35
SPhos Pd G1 / Chloro(2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) methyl-t-butylether adduct 1028206-58-7 White powder C34H45ClNO2PPd 672,57
SPhos Pd G2 / Chloro(2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl)(2′-amino-1,1′-biphenyl-2-yl)palladium(II) 1375325-64-6 White powder C38H45ClNO2PPd 720,62
SPhos Pd G3 / Methanesulfonato(2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl)(2′-amino-1,1′-biphenyl-2-yl)palladium(II) 1445085-82-4 White to light yellow powder C39H48NO5PPdS 780,26
SPhos Pd G4 / Methanesulfonato(2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl)(2′-methylamino-1,1′-biphenyl-2-yl)palladium(II) 1599466-87-1 light yellow C40H50NO5PPdS 794,29
t-BuXPhos Pd G1 / Chloro(2-di-t-butylphosphino-2′,4′,6′-tri-i-propyl-1,1′-biphenyl)[2-(2-aminoethyl)phenyl] palladium(II) 1142811-12-8 White powder C37H55ClNPPd 686,69
tBuXPhos Pd G3 / Methanesulfonato(2-di-t-butylphosphino-2′,4′,6′-tri-i-propyl-1,1′-biphenyl)(2′-amino-1,1′-biphenyl-2-yl)palladium(II) 1447963-75-8 Yellow powder C42H58NO3PPdS 794,38
t-BuBrettPhos Pd G3 / Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2′,4′,6′-tri-i-propyl-1,1′-biphenyl)(2′-amino-1,1′-biphenyl-2-yl)palladium(II) 1536473-72-9 Brownish green powder C44H62NO5PPdS 854,43
t-ButylXPhos Pd G4 / Methanesulfonato(2-di-t-butylphosphino-2′,4′,6′-tri-i-propyl-1,1′-biphenyl)(2′-methylamino-1,1′-biphenyl-2-yl)palladium(II) 1599466-89-3 cream color powder C43H60NO3PPdS 808,4
CataCXium A-Pd-G2 / Chloro[(di(1-adamantyl)-N-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) 1375477-29-4 Yellow brown powder C36H49ClNPPd 668,63
CataCXium A Pd G3 1651823-59-4 White powder C37H52NO3PPdS 728,27
CPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-2′,6′-bis(dimethylamino)-1,1′-biphenyl)(2′-amino-1,1′-biphenyl-2-yl)palladium(II) 1447963-73-6 Yellow brown powder C41H54N3O3PPdS 806,35
DavePhos Pd G3 1445085-87-9 White powder C39H49N2O3PPdS 763,28
PEPPSI™-IPr catalyst 905459-27-0 White to yellow to grayish black powder C32H40Cl3N3Pd 679,46
Dichloro[(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthyl]palladium(II) 115826-95-4 Orange powder C44H32Cl2P2Pd 800
Dichloro[(S)-(-)-2,2’-bis(diphenylphosphino)-1,1’-binaphthyl]palladium(II) 127593-28-6 Orange powder C44H32Cl2P2Pd 800
Grubbs Catalyst 1st Generation 172222-30-9 Purple black powder C43H72C2P2Ru 822,97
Grubbs Catalyst 2nd Generation 246047-72-3 Dark red to dark brown powder C46H65Cl2N2PRu 848,97
Dichloro[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]ruthenium(II) 132071-87-5 Orange powder C44H32Cl2P2Ru 794,67
Dichloro[(S)-(-)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]ruthenium(II) 134524-84-8 Orange powder C44H32Cl2P2Ru 794,67
Chloro[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl](p-cymene)ruthenium(II) chloride 145926-28-9 Orange powder C54H46Cl2P2Ru 928,87
Chloro[(S)-(-)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl](p-cymene)ruthenium(II) chloride 130004-33-0 Orange powder C54H46Cl2P2Ru 928,87
Diacetato[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]ruthenium(II) 325146-81-4 Light yellow powder C48H38O4P2Ru 841,83
Diacetato[(S)-(-)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]ruthenium(II) 261948-85-0 Yellow to brown powder C48H38O4P2Ru 841,83