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Ligand

In chemistry, a ligand plays a crucial role in the formation of coordination complexes. A ligand is defined as an ion or molecule that interacts with a central metal atom or ion to create a stable complex. This interaction fundamentally involves the transfer of electron pairs – either a lone pair from the ligand or a shared pair – to form a coordinate covalent bond. Ligands are fundamentally Lewis bases, possessing available electron pairs that they willingly donate to the electron-deficient central metal atom, which then acts as a Lewis acid, accepting those donated electrons. The strength of this bond and the resulting complex’s properties depend heavily on the nature of the ligand and the metal ion involved, showcasing a dynamic interaction at the heart of many chemical processes, including catalysis and biological systems. Understanding ligand behaviour is critical for designing and manipulating materials with specific characteristics.

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