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Nitriles


Nitriles are a class of organic compounds that contain at least one nitrile (cyano) function group. The main methods for producing nitriles in industry are ammoxidation and hydrocyanation. Other common preparations involve reactions of organic halides with cyanide salts, dehydration of aldoximes and amides, Sandmeyer reaction of aromatic diazonium salts. Nitrile groups in organic compounds can undergo a variety of reactions such as hydrolysis to first give carboxamides and then carboxylic acids, reduction to amines and alkyl nitriles can be deprotonated to nitrile anions that can alkylate a wide range of electrophiles. They also undergo nucleophilic addition reactions with organozinc compounds (Blaise reaction), alcohols (Pinner reaction) and amines. They are found in many useful compounds, including methyl cyanoacrylate in super glue, and nitrile rubber, a nitrile-containing polymer used in latex-free laboratory and medical gloves.

Product nameStructureCAS#G-code
New2-Chloro-3-methoxybenzonitrileStructure of 2-Chloro-3-methoxybenzonitrile[853331-52-9]GEO-04562
(2E)-3-[2,2′-Bithiophen]-5-yl-2-cyano-2-propenoic acidStructure of (2E)-3-[2,2'-Bithiophen]-5-yl-2-cyano-2-propenoic acid[2138319-65-8]GEO-04262
5-Bromothiophene-2-carbonitrileStructure of 5-Bromothiophene-2-carbonitrile[2160-62-5]GEO-04253
Cyanomethyl-2,3,4,6-tetra-O-acetyl-a-D-thiomannopyranoside[61145-39-9]GEO-04234
4-Isocyanato-2-trifluoromethylbenzonitrileStructure of 4-Isocyanato-2-trifluoromethylbenzonitrile[143782-18-7]GEO-04161
5-Cyano-2-fluorobenzene-1-sulfonyl chloride[1101120-80-2]GEO-04128
3-Chloro-4-methylbenzonitrileStructure of 3-Chloro-4-methylbenzonitrile[21423-81-4]GEO-04031
4-Cyanobenzenesulfonyl chloride[49584-26-1]GEO-04025
1,2-Thiazole-3-carbonitrileStructure of 1,2-Thiazole-3-carbonitrile[1452-17-1]GEO-04061
4-(Isocyanatomethyl)benzonitrileStructure of 4-(Isocyanatomethyl)benzonitrile[1205556-81-5]GEO-03844
4-Bromo-1H-pyrazole-3-carbonitrileStructure of 4-Bromo-1H-pyrazole-3-carbonitrile[288246-16-2]GEO-00562
PentafluorobenzonitrileStructure of Pentafluorobenzonitrile[773-82-0]GEO-03210
4-[(2-Cyanoethyl)methylamino]benzaldehyde[94-21-3]GEO-02609
5-Methylthiophene-2-carbonitrileStructure of 5-Methylthiophene-2-carbonitrile[72835-25-7]GEO-01953
alpha-Cyano-4-hydroxycinnamic acid butylamine salt[355011-53-9]GEO-03790
5-Amino-3-phenyl-isothiazole-4-carbonitrileStructure of 5-Amino-3-phenyl-isothiazole-4-carbonitrile[88009-93-2]GEO-03690
4-Cyanophenyl isothiocyanate[2719-32-6]GEO-03414
2-Amino-4-cyanopyridineStructure of 2-Amino-4-cyanopyridine[42182-27-4]GEO-03415
2-Chloro-4-iodo-3-pyridinecarbonitrile[1171919-75-7]GEO-03264
(4-Cyanophenyl)methanesulfonyl chloride[56105-99-8]GEO-03057
(2-Cyanophenyl)methanesulfonyl chloride[51045-34-2]GEO-03059
(4-Cyano-2-fluorophenyl)methanesulfonyl chloride[1258640-95-7]GEO-03058
(2-Cyano-4-fluorophenyl)methanesulfonyl chloride[1258652-29-7]GEO-03060
3-Methylthiophene-2-carbonitrileStructure of 3-Methylthiophene-2-carbonitrile[55406-13-8]GEO-02888
2-Fluoro-6-methylbenzonitrile[198633-76-0]GEO-02692
(E)-Methyl 3-(3-bromopyridin-4-yl)-2-cyanoacrylateN/AGEO-03565
3-Chloroisonicotinonitrile[68325-15-5]GEO-03482
(Z)-Methyl 2-cyano-3-(5-(pyridin-2-ylthio)furan-2-yl)acrylateN/AGEO-03485
(Z)-2-Isocyano-3-(5-(pyridin-2-ylthio)furan-2-yl)acrylonitrileN/AGEO-03486
(E)-Methyl 2-cyano-3-(3-methylpyridin-2-yl)acrylateN/AGEO-03490
4-(3-Bromopyridin-4-yl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileN/AGEO-03569
3′-Bromo-2,6-dimethyl-1,4-dihydro-[4,4′-bipyridine]-3,5-dicarbonitrileN/AGEO-03570
5-ChlorovaleronitrileStructure of 5-Chlorovaleronitrile[6280-87-1]GEO-00825
5-Cyano-2-fluoro-3-methylpyridineStructure of 5-Cyano-2-fluoro-3-methylpyridine[261625-67-6]GEO-00835
(E)-Methyl 2-cyano-3-(5-methylfuran-2-yl)acrylateN/AGEO-03576
Ethyl phenylcyanoacetate[4553-07-5]GEO-01372
2-((2-Chloro-4-iodopyridin-3-yl)methylene)malononitrileStructure of 2-((2-Chloro-4-iodopyridin-3-yl)methylene)malononitrile[]GEO-03645
4-(1H-Imidazol-4-yl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileStructure of 4-(1H-Imidazol-4-yl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrile[]GEO-03644
2-((5-Methylfuran-2-yl)methylene)malononitrile[81020-79-3]GEO-03572
(E)-Ethyl 3-(3-bromopyridin-4-yl)-2-cyanoacrylateStructure of (E)-Ethyl 3-(3-bromopyridin-4-yl)-2-cyanoacrylate[]GEO-03649
(E)-Methyl 2-cyano-3-(1H-imidazol-4-yl)acrylateStructure of (E)-Methyl 2-cyano-3-(1H-imidazol-4-yl)acrylate[]GEO-03648
(E)-Ethyl 2-cyano-3-(1H-imidazol-4-yl)acrylateStructure of (E)-Ethyl 2-cyano-3-(1H-imidazol-4-yl)acrylate[]GEO-03647
2-((5-(4-Methoxyphenyl)thiophen-2-yl)methylene)malononitrileN/AGEO-03579
2-(2-(Dimethylamino)-6-fluoro-4-methoxybenzylidene)malononitrileN/AGEO-03495
(Z)-Methyl 2-cyano-3-(1H-pyrrolo[2,3-b]pyridin-3-yl)acrylateN/AGEO-03496
6-(Trifluoromethyl)nicotinonitrileStructure of 6-(Trifluoromethyl)nicotinonitrile[216431-85-5]GEO-02389
2-Chloro-6-methylbenzonitrileStructure of 2-Chloro-6-methylbenzonitrile[6575-09-3]GEO-00710
(E)-2-Cyano-3-(2-(dimethylamino)-6-fluoro-4-methoxyphenyl)acrylic acidN/AGEO-03501
2-((2-Methyl-1H-indol-7-yl)methylene)malononitrileStructure of 2-((2-Methyl-1H-indol-7-yl)methylene)malononitrile[]GEO-03658
4-Cyano-3-nitrobenzoic acid[153775-42-9]GEO-02516
(Z)-Methyl 2-cyano-3-(2-methyl-1H-indol-7-yl)acrylateStructure of (Z)-Methyl 2-cyano-3-(2-methyl-1H-indol-7-yl)acrylate[]GEO-03659
3-Cyanophenyl isocyanate[16413-26-6]GEO-00847
2-((4-Bromothiophen-3-yl)methylene)malononitrileStructure of 2-((4-Bromothiophen-3-yl)methylene)malononitrile[]GEO-03663
2-(2,6-Difluoro-4-methoxybenzylidene)malononitrileN/AGEO-03502
(E)-Methyl 2-cyano-3-(2-methylpyridin-3-yl)acrylateStructure of (E)-Methyl 2-cyano-3-(2-methylpyridin-3-yl)acrylate[]GEO-03664
N-(3-Cyanophenyl)pyrrole[175134-98-2]GEO-00848
5-Cyano-2-thiophenecarboxaldehyde[21512-16-3]GEO-00851
4-(2,6-Difluoro-4-methoxyphenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileN/AGEO-03504
(E)-Methyl 3-(2-chloro-4-iodopyridin-3-yl)-2-cyanoacrylateStructure of (E)-Methyl 3-(2-chloro-4-iodopyridin-3-yl)-2-cyanoacrylate[]GEO-03668
(E)-Methyl 2-cyano-3-(5-hexylthiophen-2-yl)acrylateN/AGEO-03507
3-(Ethylamino)propionitrileStructure of 3-(Ethylamino)propionitrile[21539-47-9]GEO-01315
2-((5-Hexylthiophen-2-yl)methylene)malononitrileN/AGEO-03509
2-(3-Chloro-4-methoxybenzylidene)malononitrileN/AGEO-03596
(E)-Methyl 3-(3-chloro-4-methoxyphenyl)-2-cyanoacrylateN/AGEO-03611
(E)-2-Cyano-3-(5-hexylthiophen-2-yl)acrylic acidN/AGEO-03511
(E)-Methyl 3-(6-bromopyridin-2-yl)-2-cyanoacrylateN/AGEO-03512
2-((5-((5-Methyl-1,3,4-thiadiazol-2-yl)thio)furan-2-yl)methylene)malononitrileN/AGEO-03523
2,7,7-Trimethyl-4-(5-((5-methyl-1,3,4-thiadiazol-2-yl)thio)furan-2-yl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileN/AGEO-03524
(E)-Methyl 2-cyano-3-(5-((5-methyl-1,3,4-thiadiazol-2-yl)thio)furan-2-yl)acrylateN/AGEO-03525
4-(3-Fluorophenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileN/AGEO-03530
4-(3-Chloro-4-methoxyphenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileStructure of 4-(3-Chloro-4-methoxyphenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrile[]GEO-03613
3-Cyano-1H-pyrazole-4-carboxylic acid methylesterStructure of 3-Cyano-1H-pyrazole-4-carboxylic acid methylester[33090-69-6]GEO-00850
4-(3-Chloro-4-methoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarbonitrileStructure of 4-(3-Chloro-4-methoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarbonitrile[]GEO-03614
4-(4-Ethoxyphenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileN/AGEO-03585
(E)-Methyl 2-cyano-3-(5-methylpyridin-2-yl)acrylateN/AGEO-03535
(E)-3-(3-Chloro-4-methoxyphenyl)-2-cyanoacrylic acidStructure of (E)-3-(3-Chloro-4-methoxyphenyl)-2-cyanoacrylic acid[]GEO-03618
(E)-Methyl 2-cyano-3-(5-(4-methoxyphenyl)thiophen-2-yl)acrylateN/AGEO-03586
4-PentenenitrileStructure of 4-Pentenenitrile[592-51-8]GEO-02090
(E)-2-Cyano-3-(5-(4-methoxyphenyl)thiophen-2-yl)acrylic acidN/AGEO-03590
(E)-2-Cyano-3-(3-fluorophenyl)acrylic acidN/AGEO-03544
3,5-DibromoisonicotinonitrileStructure of 3,5-Dibromoisonicotinonitrile[870244-34-1]GEO-03678
(E)-Methyl 2-cyano-3-(1-(tetrahydro-2H-pyran-2-yl)-1H-pyrazol-5-yl)acrylateN/AGEO-03546
1H-Pyrrolo[2,3-b]pyridine-3-carbonitrile[4414-89-5]GEO-03547
2-(6-Nitro-2,3-dihydrobenzo[b][1,4]dioxin-5-yl)acetonitrileStructure of 2-(6-Nitro-2,3-dihydrobenzo[b][1,4]dioxin-5-yl)acetonitrile[]GEO-03680
2-((1-(Tetrahydro-2H-pyran-2-yl)-1H-pyrazol-5-yl)methylene)malononitrileN/AGEO-03550
3-PentoxypropionitrileStructure of 3-Pentoxypropionitrile[16728-47-5]GEO-02092
4-(4-Fluorophenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileN/AGEO-03554
5-(4-Methoxyphenyl)thiophene-2-carbonitrileN/AGEO-03594
4,5-Dicyanoimidazole[1122-28-7]GEO-01018
4-(4-Fluorophenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarbonitrileN/AGEO-03557
2-Amino-5-chlorobenzonitrileStructure of 2-Amino-5-chlorobenzonitrile[5922-60-1]GEO-00097
3-(2-Phenoxyethoxy)propiononitrileStructure of 3-(2-Phenoxyethoxy)propiononitrile[6328-54-7]GEO-02100
2-ThiopheneacetonitrileStructure of 2-Thiopheneacetonitrile[20893-30-5]GEO-02310
2-Chlorothiazole-5-carbonitrile[51640-36-9]GEO-03608
3-Cyano-6-methyl-2-pyridoneStructure of 3-Cyano-6-methyl-2-pyridone[4241-27-4]GEO-00844
4-(4-(tert-Butyl)phenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileN/AGEO-03604
N-Cyanoacetylurethane[6629-04-5]GEO-00827
5-Amino-4-cyano-3-cyanomethylpyrazoleStructure of 5-Amino-4-cyano-3-cyanomethylpyrazole[54711-21-6]GEO-00107
2,6-Dimethyl-4-(3-phenoxyphenyl)-1,4-dihydropyridine-3,5-dicarbonitrileN/AGEO-03605
(E)-Methyl 2-cyano-3-(pyridin-2-yl)acrylateN/AGEO-03603
4-(Diethylamino)butanenitrile[5336-75-4]GEO-01033
1,2,4,5-BenzenetetracarbonitrileStructure of 1,2,4,5-Benzenetetracarbonitrile[712-74-3]GEO-00253
2,7,7-Trimethyl-4-(5-methylfuran-2-yl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileN/AGEO-03599
3-HexyloxypropiononitrileStructure of 3-Hexyloxypropiononitrile[5327-02-6]GEO-01494
(2-Benzimidazolyl)acetonitrileStructure of (2-Benzimidazolyl)acetonitrile[4414-88-4]GEO-00258
(E)-Methyl 2-cyano-3-(2-methoxyphenyl)acrylateN/AGEO-03600
4-(5-Bromo-2-fluorophenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileStructure of 4-(5-Bromo-2-fluorophenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrile[]GEO-03622
4-(5-Bromo-2-fluorophenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarbonitrileStructure of 4-(5-Bromo-2-fluorophenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarbonitrile[]GEO-03619
2-Cyano-6-hydroxybenzothiazole[939-69-5]GEO-00837
(E)-Methyl 2-cyano-3-(6-methylpyridin-3-yl)acrylateStructure of (E)-Methyl 2-cyano-3-(6-methylpyridin-3-yl)acrylate[]GEO-03623
4-(2-Methoxyphenyl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileN/AGEO-03598
a-Cyano-4-hydroxycinnamic acid[28166-41-8]GEO-00838
(E)-Methyl 2-cyano-3-(thiophen-3-yl)acrylateStructure of (E)-Methyl 2-cyano-3-(thiophen-3-yl)acrylate[]GEO-03625
Pyrrole-2-carbonitrileStructure of Pyrrole-2-carbonitrile[4513-94-4]GEO-02199
2-Methyl-6-pentafluoroethyl-5-trifluoromethylpyrimidine-4-carbonitrileStructure of 2-Methyl-6-pentafluoroethyl-5-trifluoromethylpyrimidine-4-carbonitrileN/AGEO-02526
2-Cyano-6-methoxybenzothiazole[943-03-3]GEO-00839
6-Methyl-2-pyridinecarbonitrileStructure of 6-Methyl-2-pyridinecarbonitrile[1620-75-3]GEO-01725
3-n-ButoxypropionitrileStructure of 3-n-Butoxypropionitrile[6959-71-3]GEO-00607
(E)-Methyl 3-(5-bromo-2-fluorophenyl)-2-cyanoacrylateStructure of (E)-Methyl 3-(5-bromo-2-fluorophenyl)-2-cyanoacrylate[]GEO-03626
2-(5-Bromo-2-fluorobenzylidene)malononitrileStructure of 2-(5-Bromo-2-fluorobenzylidene)malononitrile[]GEO-03627
(E)-3-(5-Bromo-2-fluorophenyl)-2-cyanoacrylic acidStructure of (E)-3-(5-Bromo-2-fluorophenyl)-2-cyanoacrylic acid[]GEO-03632
4-Isobutyl-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrileStructure of 4-Isobutyl-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrile[]GEO-03628
5-Acetyl-2-amino-4-(2-furanyl)-6-methyl-4H-pyran-3-carbonitrileStructure of 5-Acetyl-2-amino-4-(2-furanyl)-6-methyl-4H-pyran-3-carbonitrile[105263-08-9]GEO-00016
5-Acetyl-2-amino-4-(4-methoxyphenyl)-6-methyl-4H-pyran-3-carbonitrileStructure of 5-Acetyl-2-amino-4-(4-methoxyphenyl)-6-methyl-4H-pyran-3-carbonitrile[105263-07-8]GEO-00017
5-Acetyl-2-amino-6-methyl-4-phenyl-4H-pyran-3-carbonitrileStructure of 5-Acetyl-2-amino-6-methyl-4-phenyl-4H-pyran-3-carbonitrile[89809-89-2]GEO-00018
(E)-3-(5-(4-Bromo-2-fluorophenyl)furan-2-yl)-2-cyanoacrylic acidStructure of (E)-3-(5-(4-Bromo-2-fluorophenyl)furan-2-yl)-2-cyanoacrylic acid[]GEO-03638
4-(5-(4-Bromo-2-fluorophenyl)furan-2-yl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarbonitrileStructure of 4-(5-(4-Bromo-2-fluorophenyl)furan-2-yl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarbonitrile[]GEO-03637
(Z)-Ethyl 2-cyano-3-(2-methyl-1H-indol-7-yl)acrylateStructure of (Z)-Ethyl 2-cyano-3-(2-methyl-1H-indol-7-yl)acrylate[]GEO-03636
2-((5-(3-Chloro-4-methoxyphenyl)furan-2-yl)methylene)malononitrileStructure of 2-((5-(3-Chloro-4-methoxyphenyl)furan-2-yl)methylene)malononitrile[]GEO-03642
(E)-Methyl 3-(5-(3-chloro-4-methoxyphenyl)furan-2-yl)-2-cyanoacrylateStructure of (E)-Methyl 3-(5-(3-chloro-4-methoxyphenyl)furan-2-yl)-2-cyanoacrylate[]GEO-03643