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Isothiocyanates / thiocyanates


They all are a class of organosulfur compounds. Thiocyanates or isothiocyanates are analogues of cyanates or isocyanates wherein oxygen is replaced by sulfur. Isothiocyanates are generally prepared by the reaction of a primary amine and carbon disulfide in aqueous ammonia to form solid ammonium dithiocarbamate salt, which is then treated with lead nitrate or tosyl chloride to yield the corresponding isothiocyanate. Reflecting their electrophilic character, isothiocyanates are susceptible to hydrolysis. They occur widely in nature and are of interest in food science and medical research. Thiocyanates are produced by the reaction of elemental sulfur or thiosulfate with cyanides. They both are used as ligands in coordination chemistry, thiocyanate being more common.

Product nameStructureCAS#G-code
2-Amino-6-thiocyanatobenzothiazoleStructure of 2-Amino-6-thiocyanatobenzothiazole[7170-77-6]GEO-00228
2-Bromoethyl isothiocyanateStructure of 2-Bromoethyl isothiocyanate[1483-41-6]GEO-03225
2-Bromo-1-fluoro-3-isothiocyanatobenzeneStructure of 2-Bromo-1-fluoro-3-isothiocyanatobenzene[364364-00-1]GEO-03723
4-Bromo-2-fluorophenylisothiocyanateStructure of 4-Bromo-2-fluorophenylisothiocyanate[81171-71-3]GEO-00453
1,4-Butane diisothiocyanateStructure of 1,4-Butane diisothiocyanate[4430-51-7]GEO-00603
1-Chloro-3-isothiocyanato-2-methoxybenzeneStructure of 1-Chloro-3-isothiocyanato-2-methoxybenzene[127142-64-7]GEO-04357
4-Cyanophenyl isothiocyanate[2719-32-6]GEO-03414
Cyclobutylisothiocyanate[6068-91-3]GEO-00855
Cyclohexyl isothiocyanate[1122-82-3]GEO-00873
Cyclopropyl isothiocyanate[56601-42-4]GEO-00892
1-Decyl isothiocyanate[24540-94-1]GEO-03388
3,4-Difluorophenyl isothiocyanate[113028-75-4]GEO-02868
2,6-Difluorophenyl isothiocyanate[207974-17-2]GEO-01061
4-Dimethylaminophenyl isothiocyanate[2131-64-8]GEO-01151
2,6-Dimethylphenyl isothiocyanate[19241-16-8]GEO-03404
2,4-Dimethylphenyl isothiocyanate[39842-01-8]GEO-01213
Ethoxycarbonyl isocyanate[19617-43-7]GEO-01300
4-Fluorobenzoyl isothiocyanateStructure of 4-Fluorobenzoyl isothiocyanate[78225-74-8]GEO-02521
4-Fluorobenzyl isothiocyanate[2740-88-7]GEO-01396
2-Fluorobenzyl isothiocyanate[64382-80-5]GEO-02493
4-Fluorophenyl isothiocyanateStructure of 4-Fluorophenyl isothiocyanate[1544-68-9]GEO-04330
2-Fluorophenyl isothiocyanate[38985-64-7]GEO-02838
3-Fluorophenyl isothiocyanate[404-72-8]GEO-01424
1,6-Hexane diisothiocyanateStructure of 1,6-Hexane diisothiocyanate[5586-70-9]GEO-02815
4-Hydroxyphenyl isothiocyanateStructure of 4-Hydroxyphenyl isothiocyanate[2131-60-4]GEO-04080
(Isocyanatomethyl)cyclopropaneStructure of (Isocyanatomethyl)cyclopropane[25694-89-7]GEO-03782
2-Isopropylphenyl isothiocyanateStructure of 2-Isopropylphenyl isothiocyanate[36176-31-5]GEO-03390
4-IsothiocyanatobenzenesulfonamideStructure of 4-Isothiocyanatobenzenesulfonamide[51908-29-3]GEO-03379
3-Isothiocyanato-2-methylbenzoic acid methyl esterStructure of 3-Isothiocyanato-2-methylbenzoic acid methyl ester[1001185-62-1]GEO-02715
4-Methoxybenzyl isothiocyanateStructure of 4-Methoxybenzyl isothiocyanate[3694-57-3]GEO-02683
3-(Methoxycarbonyl)phenyl isothiocyanateStructure of 3-(Methoxycarbonyl)phenyl isothiocyanate[3125-66-4]GEO-03396
4-Methoxycarbonylphenyl isothiocyanateStructure of 4-Methoxycarbonylphenyl isothiocyanate[3662-78-0]GEO-01676
2-Methoxyethyl isothiocyanateStructure of 2-Methoxyethyl isothiocyanate[38663-85-3]GEO-01678
4-Methoxyphenyl isothiocyanateStructure of 4-Methoxyphenyl isothiocyanate[2284-20-0]GEO-02886
3-Methylbenzyl isothiocyanateStructure of 3-Methylbenzyl isothiocyanate[3696-66-0]GEO-02500
2-Methylbenzyl isothiocyanateStructure of 2-Methylbenzyl isothiocyanate[16735-69-6]GEO-02499
4-Methyl-2-nitrophenyl isothiocyanateStructure of 4-Methyl-2-nitrophenyl isothiocyanate[17614-74-3]GEO-01898
3-(Methylthio)phenyl isothiocyanateStructure of 3-(Methylthio)phenyl isothiocyanate[51333-80-3]GEO-01966
4-Morpholinophenyl isothiocyanateStructure of 4-Morpholinophenyl isothiocyanate[51317-66-9]GEO-03910
1,8-Octane diisothiocyanateStructure of 1,8-Octane diisothiocyanate[56312-14-2]GEO-02817
Pentafluorophenyl isothiocyanateStructure of Pentafluorophenyl isothiocyanate[35923-79-6]GEO-04435
1-Pentyl isothiocyanateStructure of 1-Pentyl isothiocyanate[629-12-9]GEO-02897
1,4-Phenylene diisothiocyanateStructure of 1,4-Phenylene diisothiocyanate[4044-65-9]GEO-02685
(+)-1-Phenylethyl isothiocyanateStructure of (+)-1-Phenylethyl isothiocyanate[4478-92-6]GEO-03781
2,3,4,6-Tetra-O-acetyl-b-D-glucopyranosyl isothiocyanateStructure of 2,3,4,6-Tetra-O-acetyl-b-D-glucopyranosyl isothiocyanate[14152-97-7]GEO-02227
2,3,4,6-Tetra-O-benzoyl-b-D-glucopyranosyl isothiocyanateStructure of 2,3,4,6-Tetra-O-benzoyl-b-D-glucopyranosyl isothiocyanate[132413-50-4]GEO-02230
1-Tetradecyl isothiocyanateStructure of 1-Tetradecyl isothiocyanate[3224-48-4]GEO-03397
2-Tetrahydrofurfuryl isothiocyanateStructure of 2-Tetrahydrofurfuryl isothiocyanate[36810-87-4]GEO-02899
2,4,6-Trichlorophenyl isothiocyanateStructure of 2,4,6-Trichlorophenyl isothiocyanate[22134-07-2]GEO-02358
1,2,5-Trifluoro-3-isothiocyanatobenzeneStructure of 1,2,5-Trifluoro-3-isothiocyanatobenzene[362690-55-9]GEO-03993
3-(Trifluoromethyl)phenyl isothiocyanateStructure of 3-(Trifluoromethyl)phenyl isothiocyanate[1840-19-3]GEO-02620
3,4,5-Trimethoxyphenyl isothiocyanateStructure of 3,4,5-Trimethoxyphenyl isothiocyanate[35967-24-9]GEO-03398